OK not resolved, its just happened again
So a bit of history: Scheduler has been in place on this course for the past year. Last year (running on Moodle 2.6) all was fine, students were introduced to the scheduler and it was soon being widely used. We did a upgrade to Moodle over the summer (to 2.8 - version details above) and when the students returned in September and started using the scheduler we had problems with this happening to every student. I scrolled the forums here and tried various tweaks (ie, unlimited to 10, making sure no groups etc) but couldn't find a resolution.
So I created a new scheduler, populated all the appointments etc. All worked fine for a few weeks but then we've started noticing the odd student having problems - as I said, its currently an intermittent problem in this one. I changed unlimited to 10 appointments. Several students have booked since then and all was starting to look ok, but its just cancelled the appointment of the latest student to book. I have been able to rebook the students onto their cancelled slot and then its booked it no problem so it doesn't even appear to be the slot that is the issue.
This course has over a 1000 students on it as its open for all our current students to be able to book an appointment with Cross College Support, and it is a well used resource. I've looked to see if there is any link between the students that are being cancelled (ie, have they booked before, is it just our new intake or is it affecting our returning students. have they booked appointments before) but there is no link that I can see. It not even a case of its hitting every 10 students that try to book.
At a complete loss of what to try next. We have another course with a site wide scheduler that all our students can use for booking careers appointments and this one may also be experiencing these problems (although its also not so heavily used so hard to tell)
Sue