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Start with a few books. Packet Publishing makes a couple of books that we have used in both learning admin stuff and How-To's. There are literally thousands of YouTube videos as well on how to "use Moodle".

Then get a bunch of books for your teachers. They will need training. Remember that PD is the most important part of any project like this.

This site should give you a good starting point. http://moodle.org/mod/data/view.php?id=7246

Remember that nobody is going to start off running in Moodle if they don't have experience with it. They will start by posting some static docs first, then try a forum or two... maybe a few links to web sites.

Later they will try an on-line quiz, add advanced content, some lessons or choices and maybe a glossary. It will take time to grow into it so start slow and get some guide books to help YOU learn what it can do so you can teach others how to use it.

Hope that helps

You can try Moodle features on a demo site, you will find many. There is one at:

http://demo.moodle.net

Also take a look at Moodle topic Blogs (like Moodleman).

To add new users, you must check
http://docs.moodle.org/en/Administrator_documentation#User_Management

Enjoy Moodle!!

The online documentation for administrators starts at http://docs.moodle.org/en/Administrator_documentation.

But, if you want to get up to speed quickly, I recommend Moodle Administration by Alex Büchner http://moodle.org/mod/data/view.php?d=55&rid=1942. That will take you through everything in a logical order.