In some themes you can alter the Bootstrap variables, and then generate new .css from the .less. One of those variables controls the roundness of the corners, so if that's the kind of theme you are dealing with then a few variable changes should get rid of most rounded corners in one go.
In defaul Bootstrap those options are:
@baseBorderRadius: 4px;
@borderRadiusLarge: 6px;
@borderRadiusSmall: 3px;
And setting them all to 0 should get rid of rounded corners. I don't know if this is possible with the theme you currently use, but it's something we do to achieve pointy corners in a Bootstrap 3-based theme, so possibly worth looking into. A similar technique could probably remove most borders as well.