what are you running as your db server? - is it on the same server? - sometimes you can improve performance a bit by seperating out the db/web server.
Which accellerator are you using? - are you using the microsoft one (wincache I think it's called)
IIS 6 is a bit old too...
Microsoft has a web application gallery (which includes Moodle) - it installs PHP/IIS/Moodle in a pretty quick/semi-tuned manner. (only supports Mysql at this stage though) - if you have the option of creating a new VM running a newer version of win server I'd suggest using that installer to set the server up - then replace the moodle db/files with the ones on your old server.
http://www.microsoft.com/web/gallery/moodle.aspx
- you could even just use the gallery to install PHP/wincache and do the moodle/db level install yourself.
Even better might be to convince your ITS team to install a linux vm (moodle docs has a lot more info on tuning/installing moodle on a linux box than windows)
But none of this is guarenteed to improve the performance - you might just not have enough hardware available to run Moodle 2.x (which is more resource intensive in some areas) - also your usage of Moodle may have increased compared to last year so your server will have to work even harder due to the increased traffic.