Great discussion, guys, and thanks to David for bringing this point up.
Outside of the technical realm, my reason for moving to mysql is purely one of standards. I have a number of apps running in MS SQLServer and mysql, with Moodle being the only postgres app. I'd rather run two DB's rather than three, and migrating the others over to PG isn't an option.
An interesting observation that the majority of technical info for Moodle revolves around mysql instead of Postgres, which of course means more mental arithmetic when trying to apply the "logic" from examples.
So, assuming I've taken everyone's comments under advisement and still want to proceed migrating, what's the best route? I see my options as follows:
1) Manually export each course from the Moodle-postgres and import into Moodle-mysql. Time-intensive, but relies on Moodle backup/restore to make sure life looks good.
2) Use some manual PHP scripts to copy the tables and data over between the databases. Risky, since I'm not sure the table sequences and indexes will get set up properly, and since I'm not a DBA...
Thanks for sharing your opinions! Derry